nO2 = 6.72/22.4 = 0.3 (mol) 

BTKL : 

mKMnO4 = 116.8 + 0.3*32 = 126.4 (g) 

nKMnO4 = 126.4/158 = 0.8 (mol) 

2KMnO4 -to-> K2MnO4 + MnO2 + O2 

0.6_________________________0.3 

H% = 0.6/0.8 * 100% = 75% 

\(n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol) \\m = m_{chất\ rắn} + m_{O_2} = 116,8 + 0,3.32 = 126,4(gam)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,3.2 = 0,6(mol)\\ H = \dfrac{0,6.158}{126,4}.100\%= 75\%\)

PTHH :

2KMnO4 -----> K2MnO4 + MnO2 + O2

x...........................x/2...............x/2............x/2

Gọi x là số mol KMnO4 phản ứng

=> m_K2MnO4 = 98,5x (g)

m_MnO2 = 43,5x (g)

m_{KMnO4 (dư)} = 31,6 - 158x (g)

=> m_{CR (sau)} = 98,5x + 43,5x + 31,6 - 158x

=> 29,04 = -16x + 31,6

=> 2,56 = 16x

=> 0,16 = x (mol)

Theo đề bài :

m_KMnO4 = 31,6 (g)

=> n_KMnO4 = 31,6 : 158 = 0,2 (mol)

=> H% = 0,16 : 0,2 . 100% = 80 %

mO2 = 31,6 - 29,2 = 2,4 g

nO2 = 2,4/32 = 0,075 mol

2KMnO4 → K2MnO4 + MnO2 + O2

0,15 ← 0,075

mKMnO4 = 0,15.158 = 23,7 g

H = \(\dfrac{23,7}{31,6}\)= 75%

Đáp án B

a) $n_{O_2} = 0,15(mol)$

\(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)

0,3                         0,15           0,15       0,15                    (mol)

$H = \dfrac{0,15.158}{63,2}.100\% = 37,5\%$

b)

$m_B = 63,2 - 0,15.32 = 58,4(gam)$
$\%m_{K_2MnO_4} = \dfrac{0,15.197}{58,4}.100\% = 50,59\%$

$\%m_{MnO_2} = \dfrac{0,15.87}{58,4}.100\% = 22,35\%$
$\%m_{KMnO_4\ dư} = 100\% -50,59\% -22,35\% = 27,06\%$

1) \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

m_A = m_KMnO4(bđ) - m_O2 = 79 - 0,15.32 = 74,2 (g)

PTHH: 2KMnO₄ --t^o--> K₂MnO₄ + MnO₂ + O₂

               0,3<-----------0,15<----0,15<---0,15

=> \(H=\dfrac{0,3.158}{79}.100\%=60\%\)

2) 

\(\left\{{}\begin{matrix}\%m_{K_2MnO_4}=\dfrac{0,15.197}{74,2}.100\%=39,825\%\\\%m_{MnO_2}=\dfrac{0,15.87}{74,2}.100\%=17,588\%\\\%m_{KMnO_4\left(không.pư\right)}=\dfrac{79-0,3.158}{74,2}.100\%=42,587\%\end{matrix}\right.\)

3) \(n_{KMnO_4\left(không.pư\right)}=\dfrac{79}{158}-0,3=0,2\left(mol\right)\)

PTHH: 2KMnO₄ + 16HCl --> 2KCl + 2MnCl₂ + 5Cl₂ + 8H₂O

                 0,2----------------------------------->0,5

             K₂MnO₄ + 8HCl --> 2KCl + MnCl₂ + 2Cl₂ + 4H₂O

                 0,15-------------------------------->0,3

              MnO₂ + 4Hcl --> MnCl₂ + Cl₂ + 2H₂O

                0,15------------------->0,15

=> \(V_{Cl_2}=22,4\left(0,5+0,3+0,15\right)=21,28\left(l\right)\)

\(n_{KMnO_4}=\dfrac{79}{158}=0,5mol\)

\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)

\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)

0,5                                                  0,15

a)\(m_{KMnO_4}=0,15\cdot197=29,55g\)

\(m_{MnO_2}=0,15\cdot87=13,05g\)

\(m_{CRắn}=m_{KMnO_4}+m_{MnO_2}=29,55+13,05=42,6g\)

\(n_{KMnO_4pư}=0,15\cdot2=0,3mol\)

\(H=\dfrac{0,3}{0,5}\cdot100\%=60\%\)

b)\(m_{O_2}=0,15\cdot32=4,8g\)

\(\%m_{K_2MnO_4}=\dfrac{29,55}{42,6}\cdot100\%=69,37\%\)

\(\%m_{MnO_2}=100\%-69,37\%=30,63\%\)

Có: \(M_{KMnO_4}=39+55+16.4=158\left(đvc\right)\) 

\(\Rightarrow n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{31,6}{158}=0,2\)(g/mol)

\(n_{O_2}=\dfrac{V_{O_2}}{22,4}=\dfrac{1,792}{22,4}=0,08\)

Ta có    \(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)

Số gam \(KMnO_4\) theo lý thuyết phản ứng là 31,6 ( gam)

Số gam \(KMnO_4\) theo  thực tế phản ứng là 0,16.158=25,28 (gam)

Hiệu suất của phản ứng là \(\dfrac{25,28}{31,6}.100\%=80\%\) 

Vậy hiệu suất của phản ứng là 80%

Sửa đề: 31,5 gam KMnO₄

PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)

Ta có: \(\left\{{}\begin{matrix}n_{O_2\left(lý.thuyết\right)}=\dfrac{1}{2}n_{KMnO_2}=\dfrac{1}{2}\cdot\dfrac{31,5}{126}=0,25\left(mol\right)\\n_{O_2\left(thực\right)}=\dfrac{1,792}{22,4}=0,08\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow H\%=\dfrac{0,08}{0,25}\cdot100\%=32\%\)

\(n_{KMnO_4\left(lt\right)}=\dfrac{31.6}{158}\cdot80\%=0.16\left(mol\right)\)

\(2KMnO_4\underrightarrow{^{^{t^0}}}K_2MnO_4+MnO_2+O_2\)

\(0.16.............................................0.08\)

\(V_{O_2}=0.08\cdot22.4=1.792\left(l\right)\)

n KMnO4 = 31,6/158 =0,2(mol)

$2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2$

n O2(lt) = 1/2 n KMnO4 = 0,1(mol)

n O2(tt) = 0,1.80% = 0,08(mol)

V O2 = 0,08.22,4 = 1,792 lít